In this work, the acrylic resin coatings contained ZrO₂ nanoparticles modified with (3-glycidyloxypropyl)triethoxysilane (GPTES) were prepared by stirring with vibrating ultra-sonication method. Some characteristics of the modified ZrO₂ nanoparticles were measured by Infrared Spectroscopy (IR), X-ray Diffraction Analysis (XRD), Field Emission Scanning Electron Microscopy (FE-SEM), Thermal Gravimetric Analysis (TGA), and Dynamic Light Scattering (DLS) techniques and compared to those of the unmodified ZrO₂ nanoparticles. The effect of ZrO₂ nanoparticles modified with various GPTES content on abrasion resistance, morphology, thermal and weather stability of acrylic resin coating was investigated. The obtained results showed using 3 wt% of GPTES, the GPTES was grafted on surface of the ZrO₂ nanoparticles with the grafted amount of 0.068 mmol/g. The abrasion resistance and weather durability of acrylic resin coating were enhanced significantly in the presence of modified ZrO₂ nanoparticles. The acrylic resin coatings filled by ZrO₂ nanoparticles modified with GPTES are promising for the applications in daily life and in civil engineering construction.

在这项工作中，通过搅拌振动超声法制备了含有(3-缩水甘油氧基丙基)三乙氧基硅烷(GPTES)改性的ZrO ₂纳米粒子的丙烯酸树脂涂料。通过红外光谱 (IR)、X 射线衍射分析 (XRD)、场发射扫描电子显微镜 (FE-SEM)、热重分析 (TGA) 和动态光散射 (DLS) 测量改性 ZrO ₂纳米粒子的一些特性) 技术并与未改性的 ZrO ₂纳米粒子的技术进行比较。ZrO ₂的作用研究了不同 GPTES 含量改性的纳米粒子对丙烯酸树脂涂层的耐磨性、形态、热稳定性和耐候性的影响。所得结果表明，使用3wt%的GPTES，GPTES接枝在ZrO ₂纳米粒子的表面，接枝量为0.068 mmol/g。改性ZrO ₂纳米粒子的存在显着提高了丙烯酸树脂涂层的耐磨性和耐候性。GPTES改性ZrO ₂纳米粒子填充丙烯酸树脂涂料在日常生活和土木工程建设中的应用前景广阔。