Inspired by natural surfaces, artificial superhydrophobic coating has attracted extensive research interests. However, the application of such surface coatings for anti-fouling purposes in out-door equipment has been limited due to the lack of mechanical robustness, chemical resistance. The fabrication of superhydrophobic water-repellent coatings after mechanical damages or chemical corrosion remains a challenge. This paper described a kind of flexible superhydrophobic modified PVDF (MPVDF)/epoxy resins composites coating (SMECC) with good water repellency, strong mechanical and chemical robustness. Based on the excellent properties of MPVDF and epoxy resin, the SMECC showed strong mechanical robustness under cyclic tape stripping and taber abrasion. The obtained coating can continuous exposure to UV light or high corrosive medium (hydrochloric acid and sodium hydroxide solutions) for several days while maintaining super-hydrophobicity (WCA > 158°, WSA < 1°), and has adaptability on different substrates. In addition, the mechanical flexibility of our coating ensures high speed drip resistance anti-moisture stabilities. These developed coatings have a wide range of robustness and scalability, making them promising candidates for a variety of harsh applications environments and even under-water conditions.

受自然表面的启发，人造超疏水涂层引起了广泛的研究兴趣。然而，由于缺乏机械强度和耐化学性，此类表面涂层在户外设备中用于防污目的的应用受到限制。在机械损坏或化学腐蚀后制造超疏水防水涂层仍然是一个挑战。本文描述了一种具有良好拒水性、强机械和化学稳定性的柔性超疏水改性 PVDF (MPVDF)/环氧树脂复合涂层 (SMECC)。基于 MPVDF 和环氧树脂的优异性能，SMECC 在循环胶带剥离和泰伯磨损下表现出很强的机械强度。所得涂层在保持超疏水性（WCA > 158°，WSA < 1°）的情况下，可以连续暴露在紫外光或高腐蚀性介质（盐酸和氢氧化钠溶液）下数天，对不同基材具有适应性。此外，我们涂层的机械柔韧性确保了高速抗滴落和防潮稳定性。这些开发的涂层具有广泛的坚固性和可扩展性，使它们成为各种恶劣应用环境甚至水下条件的有希望的候选者。