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Nitridic Analogs of Micas AESi3P4N10(NH)2 (AE=Mg, Mg0.94Ca0.06, Ca, Sr)
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-12-02 , DOI: 10.1002/anie.202114902 Lucien Eisenburger 1 , Philipp Strobel 2 , Peter J Schmidt 2 , Thomas Bräuniger 1 , Jonathan Wright 3 , Eleanor Lawrence Bright 3 , Carlotta Giacobbe 3 , Oliver Oeckler 4 , Wolfgang Schnick 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-12-02 , DOI: 10.1002/anie.202114902 Lucien Eisenburger 1 , Philipp Strobel 2 , Peter J Schmidt 2 , Thomas Bräuniger 1 , Jonathan Wright 3 , Eleanor Lawrence Bright 3 , Carlotta Giacobbe 3 , Oliver Oeckler 4 , Wolfgang Schnick 1
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The first nitridic analogs of micas, AESi3P4N10(NH)2 (AE=Mg, Mg0.94Ca0.06, Ca, Sr), have been prepared under high-pressure high-temperature conditions. These compounds expand the structural diversity of nitrides to mineral analogous structures, accommodating the high-pressure motif of sixfold coordinated Si. The luminescence properties of Eu2+-doped samples were investigated and narrow-band emission was revealed with emission maxima ranging from 451 nm to 492 nm.
中文翻译：
云母 AESi3P4N10(NH)2 的氮化类似物 (AE=Mg, Mg0.94Ca0.06, Ca, Sr)
云母的第一个氮化类似物AE Si 3 P 4 N 10 (NH) 2 ( AE =Mg, Mg 0.94 Ca 0.06 , Ca, Sr)是在高压高温条件下制备的。这些化合物将氮化物的结构多样性扩展到矿物类似结构，适应六重配位 Si 的高压基序。研究了Eu 2+掺杂样品的发光特性，并揭示了窄带发射，发射最大值范围为451 nm至492 nm。
更新日期：2022-01-16
中文翻译：
云母 AESi3P4N10(NH)2 的氮化类似物 (AE=Mg, Mg0.94Ca0.06, Ca, Sr)
云母的第一个氮化类似物AE Si 3 P 4 N 10 (NH) 2 ( AE =Mg, Mg 0.94 Ca 0.06 , Ca, Sr)是在高压高温条件下制备的。这些化合物将氮化物的结构多样性扩展到矿物类似结构，适应六重配位 Si 的高压基序。研究了Eu 2+掺杂样品的发光特性，并揭示了窄带发射，发射最大值范围为451 nm至492 nm。
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