Guest-Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage,Angewandte Chemie International Edition

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Guest-Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-12-01 , DOI: 10.1002/anie.202115468
André P Birvé ₁ , Harshal D Patel ₁ , Jason R Price ₂ , Witold M Bloch ₁ , Thomas Fallon ₁

Affiliation

The first metallo-supramolecular M₂L₄ cages bearing shape-shifting bullvalene ligands are prepared. The enormous potential complexity is limited by geometric constraints in solution, which converge to a single isomer in the solid state. Through detailed experimental and computational analysis, we map the fluxional nature of these systems.