Transition-Metal-Catalyzed Cross-Coupling and Sequential Reactions of Azides with Isocyanides,Advanced Synthesis & Catalysis

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Transition-Metal-Catalyzed Cross-Coupling and Sequential Reactions of Azides with Isocyanides
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-11-22 , DOI: 10.1002/adsc.202101107
Zhen Zhang ₁ , Pengpeng Tan ₁ , Wenxu Chang ₂ , Zhenhua Zhang ₃

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Transition-metal-catalyzed cross-coupling reaction of azides with isocyanides, as a new type of nitrene transformation, has become an expeditious method to prepare carbodiimides. Considering the compatibility of this coupling process with other systems, transition-metal-catalyzed sequential reactions have become more popular in recent years. These remarkable advances not only involve many interesting reaction processes, but also provide useful strategies for the construction of nitrogen-containing structures, such as guanidines, amidines, isoureas, and heterocyclic compounds. This review will present a comprehensive picture of the development of transition-metal-catalyzed coupling process of azides with isocyanides and their applications in the preparation of nitrogen-containing compounds. Catalytic coupling reactions followed by nucleophilic additions will be briefly introduced here. Most recent advances in catalytic cascade reactions involving a coupling process will be highlighted and make up the main part of this review.

中文翻译：

过渡金属催化的叠氮化物与异氰化物的交叉偶联和顺序反应

过渡金属催化叠氮化物与异氰化物的交叉偶联反应作为一种新型的氮烯转化方法，已成为制备碳二亚胺的快捷方法。考虑到这种偶联过程与其他系统的兼容性，过渡金属催化的序贯反应近年来变得越来越流行。这些显着的进展不仅涉及许多有趣的反应过程，而且为构建含氮结构（如胍、脒、异脲和杂环化合物）提供了有用的策略。本综述将全面介绍叠氮化物与异氰化物的过渡金属催化偶联过程的发展及其在制备含氮化合物中的应用。这里将简要介绍亲核加成后的催化偶联反应。将重点介绍涉及偶联过程的催化级联反应的最新进展，并构成本综述的主要部分。

更新日期：2021-12-21

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