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Electrochromic TiO2 films by a facile solvothermal process: Effect of ethanol content on growth and performance
Optical Materials ( IF 3.8 ) Pub Date : 2021-11-19 , DOI: 10.1016/j.optmat.2021.111744
Bo Zhang 1, 2 , Guoyue Xu 2 , Shengli Liu 1 , Fengfeng Chi 1 , Yuanyuan Tian 1
Affiliation  

The TiO2 films are directly prepared on FTO-coated substrates by a facile solvothermal method. The influence of ethanol content in precursor on the microstructure and electrochromic performance of TiO2 films is studied. The X-Ray diffraction result shows that the prepared TiO2 samples are crystalline. When the ethanol contents of 20% and 30%, the TiO2 films show (010) preferred orientation and fluffy porous structure. Analysis results of electrochromic performance indicate that the TiO2 film synthesized with the ethanol content of 20% exhibits the highest transmittance modulation (ΔT780 nm = 75.4%), the fastest switching times (bleaching time: 8.9 s, coloration time: 12.2 s) and the largest coloration efficiency (CE = 78 cm2/C). In addition, the cyclic voltammetry measurements confirm that the film synthesized with the ethanol content of 20% exhibits high cyclic stability (1000 cycles).



中文翻译:

通过简便的溶剂热工艺制备电致变色 TiO2 薄膜:乙醇含量对生长和性能的影响

TiO 2薄膜是通过简便的溶剂热法直接在 FTO 涂层的基材上制备的。研究了前驱体中乙醇含量对TiO 2薄膜微观结构和电致变色性能的影响。X射线衍射结果表明制备的TiO 2样品为结晶态。当为20%和30%的乙醇含量,在TiO 2膜显示(010)择优取向和蓬松多孔结构。电致变色性能分析结果表明,乙醇含量为20%时合成的TiO 2薄膜表现出最高的透射率调制(Δ T 780 nm = 75.4%),最快的转换时间(漂白时间:8.9 s,着色时间:12.2 s)和最大的着色效率(CE  = 78 cm 2 /C)。此外,循环伏安测量证实,以 20% 的乙醇含量合成的薄膜表现出高循环稳定性(1000 次循环)。

更新日期:2021-11-20
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