As an emerging scintillation material, metal halide perovskite (${\text{CsPbX}}_3$) has been deemed the most potentially valuable candidate in X-ray detection and medical imaging. Nevertheless, it is a continuing challenge to implement efficient radioluminescence (RL) with high radiation stability and moisture resistance. Moreover, the optimized luminescence properties and excellent uniformity of ${\text{CsPbX}}_3$ glass are also key points for obtaining perfect X-ray images. Herein, we have successfully precipitated ${\mathrm{Eu}}^{3+}$-doped ${\text{CsPbBr}}_3$ nanocrystals (NCs) with improved photoluminescence quantum yield ($\approx 58.6\%$) because partial ${\mathrm{Eu}}^{3+}$ entered the perovskite lattice in a robust borosilicate glass matrix by in situ crystallization. The small amount of Eu addition made the lattice of NCs shrink and promoted uniform distribution of ${\text{CsPbBr}}_3$ NCs in the glass, which effectively reduced the light scattering of the sample. Subsequently, multimodal RL intensity of the ${\text{CsPbBr}}_3/{\text{CsPbBr}}_3$:xEu NCs glasses (CPB-0Eu/CPB-xEu) as a function of X-ray dose rate showed a superlinear relationship to the benefit of obtaining satisfactory X-ray images. Also, the outstanding radiation stability and water resistance of CPB-xEu were confirmed due to the protection of the robust glass matrix. Finally, an X-ray imaging system using a CPB-xEu scintillator was constructed, and the spring in the opaque sample was legibly detected under the motivation of X-rays, indicating that ${\text{CsPbX}}_3$ glasses possess extensive application prospects in terms of X-ray detection and medical imaging.

中文翻译：

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用于 X 射线检测和成像的增强型多峰发光和超高稳定性 Eu3+ 掺杂 CsPbBr3 玻璃

作为一种新兴的闪烁材料，金属卤化物钙钛矿（${\text{铂族化合物}}_3$) 已被认为是 X 射线检测和医学成像中最具潜在价值的候选者。然而，实现具有高辐射稳定性和防潮性的高效辐射发光（RL）仍然是一个持续的挑战。此外，优化的发光性能和优异的均匀性${\text{铂族化合物}}_3$玻璃也是获得完美 X 射线图像的关键点。到这里，我们已经成功沉淀了${我}^{3+}$-掺杂 ${\text{溴化铅}}_3$ 具有改进的光致发光量子产率的纳米晶体（NCs）（$\approx 58.6\%$) 因为部分 ${我}^{3+}$通过原位结晶进入坚固的硼硅酸盐玻璃基质中的钙钛矿晶格。少量的 Eu 加入使 NCs 的晶格收缩并促进了 NCs 的均匀分布${\text{溴化铅}}_3$玻璃中的 NCs，有效地减少了样品的光散射。随后，多模态 RL 强度${\text{溴化铅}}_3/{\text{溴化铅}}_3$: x Eu NCs 玻璃 (CPB-0Eu/CPB- x Eu) 作为 X 射线剂量率的函数显示出与获得令人满意的 X 射线图像的益处的超线性关系。此外，由于坚固的玻璃基质的保护，CPB- x Eu出色的辐射稳定性和防水性也得到了证实。最后，构建了使用 CPB- x Eu 闪烁体的 X 射线成像系统，在 X 射线的激励下清晰地检测到不透明样品中的弹簧，表明${\text{铂族化合物}}_3$ 眼镜在X射线检测和医学成像方面具有广泛的应用前景。