Supramolecular polymerization and supramolecular polymeric materials have attracted a great deal of attention over the past three decades. Traditional methods for fabricating supramolecular polymers and materials mainly focus on the self-assembly of building units, including the noncovalent polymerization of covalent monomers and the noncovalent cross-linking of linear polymers. Lately, we come up with a novel concept of supramonomer, which refers to a monomer that is fabricated by noncovalent interactions and is able to undergo covalent polymerization or noncovalent polymerization. Since then, plenty of supramolecular polymers and supramolecular polymeric materials have been successfully constructed through the polymerization of supramonomers. In this trend article, we will introduce the recent progress of supramolecular polymerization and supramolecular polymeric materials based on supramonomers. Firstly, we will focus on controllable supramolecular polymerization, including controllable covalent polymerization and promoted noncovalent polymerization. Secondly, we will summarize renewable supramolecular polymeric materials on the basis of supramonomers, including degradable materials, self-healing materials, and recyclable materials. It is highly anticipated that this trend article will enrich the methodology of supramolecular polymerization and open new avenues for fabricating supramolecular polymeric materials with tailor-made properties.

在过去的三十年中，超分子聚合和超分子聚合物材料引起了极大的关注。制造超分子聚合物和材料的传统方法主要集中在构建单元的自组装，包括共价单体的非共价聚合和线性聚合物的非共价交联。最近，我们提出了一个新的超单体概念，超单体是指通过非共价相互作用制造的单体，能够进行共价聚合或非共价聚合。此后，通过超单体的聚合成功构建了大量的超分子聚合物和超分子聚合物材料。在这篇趋势文章中，我们将介绍超分子聚合和基于超单体的超分子聚合物材料的最新进展。首先，我们将关注可控超分子聚合，包括可控共价聚合和促进非共价聚合。其次，我们将在超单体的基础上总结可再生的超分子聚合物材料，包括可降解材料、自修复材料和可回收材料。人们高度期待这篇趋势文章将丰富超分子聚合的方法，并为制造具有定制特性的超分子聚合物材料开辟新的途径。包括可控共价聚合和促进非共价聚合。其次，我们将在超单体的基础上总结可再生的超分子聚合物材料，包括可降解材料、自修复材料和可回收材料。人们高度期待这篇趋势文章将丰富超分子聚合的方法，并为制造具有定制特性的超分子聚合物材料开辟新的途径。包括可控共价聚合和促进非共价聚合。其次，我们将在超单体的基础上总结可再生的超分子聚合物材料，包括可降解材料、自修复材料和可回收材料。人们高度期待这篇趋势文章将丰富超分子聚合的方法，并为制造具有定制特性的超分子聚合物材料开辟新的途径。