Emergence of a Promiscuous Peroxidase Under Non-Equilibrium Conditions**,Angewandte Chemie International Edition

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Emergence of a Promiscuous Peroxidase Under Non-Equilibrium Conditions**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-11-12 , DOI: 10.1002/anie.202111857
Sumit Pal ₁ , Antara Reja ₁ , Subhajit Bal ₁ , Baishakhi Tikader ₂ , Dibyendu Das ₁

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Substrate-induced generation of a transient catalytic microphase was shown in presence of a single amino acid functionalized fatty acid and a cofactor hemin. The transient state exhibited acceleration of catalytic potential resulting in degradation of the substrate. Furthermore, latent catalytic function was displayed to hydrolyze a precursor to yield the same substrate suggesting promiscuous activity.