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Accelerated CO2 transport on the surface-tuned Ag nanoparticles by p-benzoquinone
Journal of Industrial and Engineering Chemistry ( IF 5.9 ) Pub Date : 2021-11-10 , DOI: 10.1016/j.jiec.2021.11.006
Beom Jun Kim 1 , Sang Wook Kang 1, 2
Affiliation  

The polarized silver nanoparticles (AgNPs) were used as carriers in CO2 separation through facilitated transport. AgNPs were polarized and stabilized by adding p-benzoquinone (p-BQ). This polymeric composite membrane was used for CO2/N2 separation, and showed high-selective performance. Through CO2 and N2 gas permeation experiment, it was confirmed that these membranes showed ideal selectivity of 117 or more. These separation performances were significantly improved compared to pristine PVP and were due to the selective and reversible interaction between polar CO2 molecules and AgNPs polarized by p-BQ. Positive charged density on surface of particles was analyzed by XPS and it was found that it could accelerate the transport of CO2 molecules through dipole-dipole interaction.



中文翻译:

对苯醌加速 CO2 在表面调谐银纳米粒子上的传输

极化银纳米粒子 (AgNPs) 被用作通过促进传输分离CO 2的载体。通过添加对苯醌 ( p -BQ)使 AgNPs 极化和稳定。该高分子复合膜用于CO 2 /N 2分离,具有高选择性。通过CO 2和N 2气体渗透实验,证实这些膜表现出117或更高的理想选择性。与原始 PVP 相比,这些分离性能显着提高,这是由于极性 CO 2分子和被p极化的 AgNPs之间的选择性和可逆相互作用-BQ。通过XPS分析颗粒表面的正电荷密度,发现它可以通过偶极-偶极相互作用加速CO 2分子的传输。

更新日期:2022-01-19
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