当前位置: X-MOL 学术Angew. Chem. Int. Ed. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Electrochemical Trifluoromethoxylation of (Hetero)aromatics with a Trifluoromethyl Source and Oxygen
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2021-11-09 , DOI: 10.1002/anie.202114048
Yao Ouyang 1 , Xiu-Hua Xu 1 , Feng-Ling Qing 1
Affiliation  

A conceptually new trifluoromethoxylation reaction through the combination of readily available trifluoromethylating reagent and oxygen under electrochemical conditions was developed. The synthetic utility of this new protocol is illustrated by the C−H trifluoromethoxylation of (hetero)arenes and biorelevant molecules.
image


中文翻译:

(杂)芳烃与三氟甲基源和氧气的电化学三氟甲氧基化

通过在电化学条件下容易获得的三氟甲基化试剂和氧气的组合,开发了一种概念上新的三氟甲氧基化反应。这种新协议的合成效用通过(杂)芳烃和生物相关分子的 C-H 三氟甲氧基化来说明。
图片
更新日期:2021-12-02
down
wechat
bug