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Electrophoretic Codeposition of MoOx/MoS2 Thin Film for Platinum-Free Counter Electrode in Quantum Dot Solar Cells
International Journal of Photoenergy ( IF 2.1 ) Pub Date : 2021-11-09 , DOI: 10.1155/2021/7691202
Thanh Tung Nguyen 1 , Huy Phap Ngo 2, 3 , Van Thang Le 2, 4 , Le Thanh Nguyen Huynh 2, 3 , Viet Hai Le 2, 3 , Thai Hoang Nguyen 2, 3 , Hoang Long Ngo 1
Affiliation  

The MoOx/MoS2 thin films were manufactured on conducting glass (FTO) from the ethanolic mixture of colloidal molybdenum disulfide (MoS2) and molybdenum oxides (MoOx) by electrophoretic deposition method and were used for counter electrode of quantum dot solar cells. Different ramp-rate conditions for electrophoretic deposition as well as bias potential were investigated in an attempt to get the highest possible electrocatalytic activity of polysulfide (S2-/Sn2-) redox couple. In this research, interestingly, by simply using CdS/CdSe/ZnS photoanode and polysulfide electrolyte under 1000 W.m−2 AM 1.5 G illumination, the power conversion efficiency of MoOx/MoS2-counter-electrode-based QDSC was achieved up to 2.01%, which was double compared to platinum-based counter electrode of QDSCs.

中文翻译:

用于量子点太阳能电池中无铂对电极的 MoOx/MoS2 薄膜的电泳共沉积

MoO x /MoS 2薄膜是由胶体二硫化钼(MoS 2)和氧化钼(MoO x)的乙醇混合物通过电泳沉积法在导电玻璃(FTO)上制备的,用于量子点太阳能电池的对电极. 为了获得多硫化物(S 2- /S n 2-)氧化还原对的最高可能的电催化活性,研究了电泳沉积的不同斜坡速率条件以及偏置电位。在这项研究中,有趣的是,通过简单地使用 CdS/CdSe/ZnS 光阳极和 1000 Wm -2下的多硫化物电解质AM 1.5 G光照下,MoO x /MoS 2 -对电极基QDSC的功率转换效率高达2.01%,是QDSCs铂基对电极的两倍。
更新日期:2021-11-09
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