A micropore-rich mesoporous carbon (MMC) derived from ordered mesoporous carbon (OMC) is fabricated as support to prepare a highly active nano Cu₂O catalyst for methanol oxidation carbonylation. The well-dispersed ~3.3 nm Cu nanoparticles with ca. 90% purity of Cu₂O are obtained. The space-time yield and turnover frequency of DMC are significantly enhanced to $34.2\mathrm{g}{\mathrm{g}}_{\mathrm{Cu}}^{-1}{\mathrm{h}}^{-1}$ and 89.1 h⁻¹, both of which are greater than that over the mesoporous-only Cu/OMC catalyst. It is found that plentiful under-coordinated carbon atoms are formed in the introduced micropores, which serve as binding sites to immobilize Cu precursors to form the well-dispersed Cu nanoparticles. A large number of these atoms are favorable to accelerate auto-reduction of CuO to Cu₂O in kinetics and further promote to form high-purity Cu₂O. Besides, the electrons of Cu₂O are forced to transfer to the micropore surrounding, forming an electron-deficient Cu⁺ site in favor of intrinsic activity enhancement.

由有序介孔碳（OMC）衍生的富含微孔的介孔碳（MMC）作为载体制备用于甲醇氧化羰基化的高活性纳米Cu ₂ O催化剂。分散良好的~3.3 nm Cu纳米颗粒，具有约。获得90%纯度的Cu ₂ O。DMC 的时空产率和周转频率显着提高到$34.2\mathrm{G}{\mathrm{G}}_{铜}^{-1}{\mathrm{H}}^{-1}$和 89.1 h ^-1，这两者都大于仅介孔 Cu/OMC 催化剂。发现在引入的微孔中形成了大量未配位的碳原子，这些碳原子作为结合位点固定 Cu 前驱体以形成分散良好的 Cu 纳米颗粒。大量这些原子有利于在动力学上加速CuO自动还原为Cu ₂ O，进一步促进形成高纯度Cu ₂ O。此外，Cu ₂ O的电子被迫转移到周围的微孔中，形成缺电子的 Cu ⁺位点，有利于提高本征活性。