Rapid, Ordered Polymerization of Crystalline Semiconducting Covalent Triazine Frameworks,Angewandte Chemie International Edition

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Rapid, Ordered Polymerization of Crystalline Semiconducting Covalent Triazine Frameworks
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-11-05 , DOI: 10.1002/anie.202113926
Tian Sun ₁ , Yan Liang _{1,

2} , Yuxi Xu ₁

Affiliation

A microwave-assisted 2D ordered and rapid polymerization strategy is developed to prepare a series of highly crystalline and semiconducting CTFs at the hundred-gram level within 20 minutes for the first time. Abundant single-layer/few-layer crystalline 2D triazine polymer nanosheets can be obtained through simple ball-milling exfoliation of the bulk layered CTFs and exhibit remarkable photocatalytic performance.