The dark side of photocatalysis: near-infrared photoredox catalysis for organic synthesis,Organic Chemistry Frontiers

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The dark side of photocatalysis: near-infrared photoredox catalysis for organic synthesis
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2021-10-28 , DOI: 10.1039/d1qo01476e
Nicolas Sellet ₁ , Morgan Cormier ₁ , Jean-Philippe Goddard ₁

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Photoredox catalysis is now considered as a major topic in the field of organic synthesis. Recently, important progress has been made in the development of new processes involving low-energy wavelengths: Near-Infrared (NIR) photoredox catalysis. Shifting from visible to NIR light brings many advantages including mild reaction conditions and deep penetration of light. These benefits will open novel perspectives in organic synthesis. This present review highlights the recent photocatalytic systems that are able to catalyze challenging organic transformations upon NIR activation.

中文翻译：

光催化的阴暗面：用于有机合成的近红外光氧化还原催化

光氧化还原催化现在被认为是有机合成领域的一个主要课题。最近，在开发涉及低能量波长的新工艺方面取得了重要进展：近红外 (NIR) 光氧化还原催化。从可见光到近红外光的转变带来了许多优势，包括温和的反应条件和光的深度穿透。这些好处将为有机合成开辟新的视角。本综述重点介绍了最近的光催化系统，这些系统能够在 NIR 活化后催化具有挑战性的有机转化。

更新日期：2021-11-03

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