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Dynamic Restructuring of Coordinatively Unsaturated Copper Paddle Wheel Clusters to Boost Electrochemical CO2 Reduction to Hydrocarbons**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-10-27 , DOI: 10.1002/anie.202112116 Wei Zhang 1, 2 , Chuqiang Huang 1 , Jiexin Zhu 2 , Qiancheng Zhou 1 , Ruohan Yu 2 , Yali Wang 1 , Pengfei An 3 , Jing Zhang 3 , Ming Qiu 1 , Liang Zhou 2 , Liqiang Mai 2 , Zhiguo Yi 4 , Ying Yu 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-10-27 , DOI: 10.1002/anie.202112116 Wei Zhang 1, 2 , Chuqiang Huang 1 , Jiexin Zhu 2 , Qiancheng Zhou 1 , Ruohan Yu 2 , Yali Wang 1 , Pengfei An 3 , Jing Zhang 3 , Ming Qiu 1 , Liang Zhou 2 , Liqiang Mai 2 , Zhiguo Yi 4 , Ying Yu 1
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Coordinatively unsaturated Cu paddle wheel clusters were constructed with a facile “atomized trimesic acid” strategy. In situ characterization demonstrated that coordinatively unsaturated carboxylate groups in the catalyst were maintained and oxidized metal centers were stable after electrolysis, whereby they promoted a proton-coupled multi-electron transfer reaction process to produce hydrocarbons from CO2.
中文翻译：
协调不饱和铜桨轮簇的动态重组以促进电化学 CO2 还原为碳氢化合物**
采用简单的“雾化均苯三酸”策略构建了配位不饱和铜桨轮簇。原位表征表明，催化剂中的配位不饱和羧酸盐基团在电解后得到保持，氧化金属中心保持稳定，从而促进了质子耦合的多电子转移反应过程，由CO 2生产烃类。
更新日期：2021-12-02
中文翻译：
协调不饱和铜桨轮簇的动态重组以促进电化学 CO2 还原为碳氢化合物**
采用简单的“雾化均苯三酸”策略构建了配位不饱和铜桨轮簇。原位表征表明，催化剂中的配位不饱和羧酸盐基团在电解后得到保持，氧化金属中心保持稳定，从而促进了质子耦合的多电子转移反应过程，由CO 2生产烃类。
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