Nanomicelle-enhanced, asymmetric ERED-catalyzed reductions of activated olefins. Applications to 1-pot chemo- and bio-catalysis sequences in water,Chemical Communications

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Nanomicelle-enhanced, asymmetric ERED-catalyzed reductions of activated olefins. Applications to 1-pot chemo- and bio-catalysis sequences in water
Chemical Communications ( IF 4.3 ) Pub Date : 2021-10-04 , DOI: 10.1039/d1cc04774d
Nnamdi Akporji ₁ , Vani Singhania ₁ , Jade Dussart-Gautheret ₁ , Fabrice Gallou ₂ , Bruce H Lipshutz ₁

Affiliation

Bio-catalytic reactions involving ene-reductases (EREDs) in tandem with chemo-catalysis in water can be greatly enhanced by the presence of nanomicelles derived from the surfactant TPGS-750-M. Transformations are provided that illustrate the variety of sequences now possible in 1-pot as representative examples of this environmentally attractive approach to organic synthesis.

中文翻译：

纳米胶束增强、不对称 ERED 催化的活化烯烃还原。应用于水中的 1-pot 化学和生物催化序列

来自表面活性剂 TPGS-750-M 的纳米胶束的存在可以大大增强涉及烯还原酶 (ERED) 与水中化学催化的生物催化反应。提供的转换说明了现在在 1-pot 中可能出现的各种序列，作为这种对环境有吸引力的有机合成方法的代表性例子。

更新日期：2021-10-26

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