Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes,Angewandte Chemie International Edition

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Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-10-24 , DOI: 10.1002/anie.202112876
Pei-Feng Su ₁ , Ke Wang ₁ , Xuejing Peng ₁ , Xiaobo Pang ₁ , Peng Guo ₁ , Xing-Zhong Shu ₁

Affiliation

A new C−Ge bond-forming framework was established, which bridges a gap between a recently developed mild coupling technique and organogermane chemistry. The method provides a mild approach for the synthesis of both aryl and alkenyl germanes, with improved molecular diversity and structural complexity, using readily available carbon electrophiles and chlorogermanes as starting materials.