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Nickel-Catalyzed Reductive C−Ge Coupling of Aryl/Alkenyl Electrophiles with Chlorogermanes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-10-24 , DOI: 10.1002/anie.202112876
Pei-Feng Su 1 , Ke Wang 1 , Xuejing Peng 1 , Xiaobo Pang 1 , Peng Guo 1 , Xing-Zhong Shu 1
Affiliation  

A new C−Ge bond-forming framework was established, which bridges a gap between a recently developed mild coupling technique and organogermane chemistry. The method provides a mild approach for the synthesis of both aryl and alkenyl germanes, with improved molecular diversity and structural complexity, using readily available carbon electrophiles and chlorogermanes as starting materials.
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中文翻译:

芳基/烯基亲电试剂与氯锗烷的镍催化还原 C−Ge 偶联

建立了一种新的 C−Ge 键形成框架,它弥合了最近开发的温和耦合技术和有机锗烷化学之间的差距。该方法为芳基和烯基锗烷的合成提供了一种温和的方法,具有改进的分子多样性和结构复杂性,使用容易获得的碳亲电子试剂和氯锗烷作为起始材料。
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更新日期:2021-12-06
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