Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China.
Key Laboratory for Advanced Materials, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China.
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China.
Physics Department and Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, 3663 North Zhongshan Road, Shanghai, 200062, China.
Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201204, China.
School of Chemistry and Chemical Engineering, The Queen's University of Belfast, Belfast, BT9 5AG, UK.
A S-HKUST-1 precatalyst with stable isolated Cu−S motifs was prepared by the strategy of local sulfur doping. The precatalyst can be in situ reconstructed to obtain a Cu(S) matrix with active biphasic copper/copper sulfide interfaces, which delivers a current density of 400 mA cm−2 with Faradaic efficiency of ethylene to 57.2 % in the flow cell.
中文翻译：
基于金属-有机骨架的预催化剂中分离的 Cu-S 基团实现高度乙烯选择性电催化 CO2 还原
通过局部硫掺杂策略制备了具有稳定分离的 Cu-S 基序的 S-HKUST-1 预催化剂。可以原位重构预催化剂以获得具有活性双相铜/硫化铜界面的 Cu(S) 基质，其提供 400 mA cm -2的电流密度，乙烯的法拉第效率在流通池中达到 57.2%。
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