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Construction of AuNPs/Cu,I-CD-based colorimetric sensor: Catalytic oxidation of TBHQ and the catalytic inhibition of HCHO
Food Chemistry ( IF 8.5 ) Pub Date : 2021-10-20 , DOI: 10.1016/j.foodchem.2021.131438
Qiulan Li 1 , Dezhi Yang 1 , Sai Kumar Tammina 2 , Yaling Yang 1
Affiliation  

Various research groups have been paying huge attention to tune the metal states in metal–carbon hybrid materials. Herein, a mixed-valence copper-iodine co-doped carbon dots (Cu,I-CDs, Cu2+/Cu+/Cu0) were prepared through a one-step hydrothermal method, which displayed an intrinsic reduction performance under given conditions. Moreover, AuNPs/Cu,I-CDs composite was fabricated using Cu,I-CDs as reductant and stabilizer. Among them, the AuNPs/Cu,I-CDs composite exhibited the highest oxidase- and peroxidase-like activities, which was used for the colorimetric detection of tert-butyl hydroquinone (TBHQ), with the detection limits of 23.45 μg/kg. Interestingly, the catalytic oxidation of TBHQ to oxidized TBHQ (TQ) could be inhibited by formaldehyde (HCHO). Therefore, a colorimetric sensor for HCHO was developed with the detection limit 0.335 mg/L. The catalytic mechanism for TBHQ was investigated by employing scavengers of different reactive species, indicating the significant roles of •O2 in the catalytic process. Therefore, it is believed that the as-prepared AuNPs/Cu,I-CDs nanozyme has promising potential applications in the fields of biomedicine and food safety.



中文翻译:

基于AuNPs/Cu,I-CD的比色传感器的构建:TBHQ的催化氧化和HCHO的催化抑制

各种研究小组一直非常关注调整金属-碳杂化材料中的金属状态。在此,通过一步水热法制备了混合价铜碘共掺杂碳点(Cu,I-CDs,Cu 2+ /Cu + /Cu 0),在给定条件下表现出固有的还原性能. 此外,使用Cu,I-CDs作为还原剂和稳定剂制备了AuNPs/Cu,I-CDs复合材料。其中,AuNPs/Cu,I-CDs 复合物表现出最高的氧化酶和过氧化物酶活性,用于比色检测-丁基氢醌(TBHQ),检测限为23.45 μg/kg。有趣的是,甲醛 (HCHO) 可以抑制 TBHQ 催化氧化为氧化 TBHQ (TQ)。因此,开发了检测限为 0.335 mg/L 的 HCHO 比色传感器。通过使用不同活性物种的清除剂研究了 TBHQ 的催化机制,表明 •O 2 -在催化过程中的重要作用。因此,所制备的AuNPs/Cu,I-CDs纳米酶在生物医学和食品安全领域具有广阔的应用前景。

更新日期:2021-11-03
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