Fullerenes, Nanotubes and Carbon Nanostructures ( IF 2.1 ) Pub Date : 2021-10-18 , DOI: 10.1080/1536383x.2021.1992390 Urol K. Makhmanov 1, 2 , Abdulmutallib M. Kokhkharov 1 , Sagdilla A. Bakhramov 1 , Shaxboz A. Esanov 1 , Donats Erts 3
Abstract
The behavior of self-assembly of C60 molecules in solutions of C60/hexane/xylene were studied by the methods of refractometry, ultraviolet–visible spectroscopy and dynamic light scattering (DLS). It was experimentally shown that with a slight increase in either the concentration of fullerene C60 or the volume fraction of xylene in a C60/hexane/xylene solution, the refractive index of the medium increases. Increasing the xylene content of the C60/hexane/xylene system leads to significant changes in charge transfer between solute and solvent, which, in particular, exhibit both a positive solvatochromic effect and a hypochromic effect in a strong absorption band at ∼328.8 nm. It was established by the DLS method that with an increase in the concentration of C60 in the C60/hexane solution from 20 to 30 mg/dm3, the maximum radius of the synthesized nanoclusters in solutions changed from ∼6.25 nm to ∼17.2 nm, and also with an increase in the mole fraction of xylene in the C60/hexane/xylene system, the cluster size gradually decreases.
中文翻译:
C60富勒烯分子在己烷-二甲苯溶剂体系中的自组装
摘要
采用折光法、紫外-可见光谱法和动态光散射(DLS)等方法研究了C 60分子在C 60 /己烷/二甲苯溶液中的自组装行为。实验表明,随着富勒烯 C 60浓度或 C 60 /己烷/二甲苯溶液中二甲苯体积分数的轻微增加,介质的折射率增加。增加 C 60的二甲苯含量/己烷/二甲苯体系导致溶质和溶剂之间的电荷转移发生显着变化,特别是在~328.8 nm的强吸收带中表现出正溶剂化变色效应和减色效应。通过DLS方法确定,随着C 60 /己烷溶液中C 60 浓度从20增加到30 mg/dm 3 ,溶液中合成的纳米团簇的最大半径从~6.25 nm变为~17.2 nm,并且随着C 60 /己烷/二甲苯体系中二甲苯摩尔分数的增加,簇大小逐渐减小。