Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2021-10-16 , DOI: 10.1016/j.jhazmat.2021.127530 Hangzhou Xu 1 , Jing Zhang 2 , Wenjuan Wang 3 , Yizhen Li 2 , Haiyan Pei 4
The increasing frequency and intensity of taste- and odour-producing cyanobacteria in water sources is a growing global issue. Odour events caused by 2-methylisoborneol (2-MIB) mainly arising from filamentous cyanobacteria have been a very common problem in water supply. Removal rates of filamentous cyanobacteria and 2-MIB by conventional water treatment, such as coagulation, and disinfection treatment processes is low. Hence, a moderate pre-ozonation of cyanobacteria (with little cell damage) was proposed in this study as an enhanced coagulation step to remove filamentous cyanobacteria and intracellular 2-MIB effectively, while avoiding the release of intracellular 2-MIB. A post-peroxone (O3/H2O2) process was applied after sand filtration to degrade the residual dissolved 2-MIB. Results show that moderate pre-ozonation (0.2 mg/L O3 oxidation for 20 min) can substantially enhance the coagulation efficiency for algae, with low cell lysis and high cell viability. Furthermore, 2.0 mg/L O3 combined with 2.0 mg/L H2O2 can degrade the residual dissolved 2-MIB nearly 100% after 20 min reaction. Based on the optimal dosages, a 0.6 m3/h pilot system, including pre-ozonation, coagulation and sedimentation, sand filtration, and post-peroxone processes, was continuously run for 14 days, and it was found that the proposed process can effectively and stably remove filamentous cyanobacteria and 2-MIB.
中文翻译:
适度的预臭氧化与后过氧酮过程相结合,可有效去除丝状蓝藻和 2-MIB:从实验室到中试规模研究
水源中产生味道和气味的蓝藻的频率和强度越来越高,这是一个日益严重的全球性问题。由主要由丝状蓝藻引起的 2-甲基异冰片 (2-MIB) 引起的气味事件一直是供水中非常普遍的问题。传统水处理如混凝和消毒处理工艺对丝状蓝藻和 2-MIB 的去除率较低。因此,本研究提出了对蓝藻进行适度的预臭氧化(几乎没有细胞损伤)作为增强的凝血步骤,以有效去除丝状蓝藻和细胞内 2-MIB,同时避免细胞内 2-MIB 的释放。A 后过氧化物 (O 3 /H 2 O 2) 工艺在砂滤后应用以降解残留的溶解 2-MIB。结果表明,适度的预臭氧化(0.2 mg/LO 3氧化 20 分钟)可以显着提高藻类的凝结效率,具有低细胞裂解和高细胞活力。此外,2.0 mg/LO 3与2.0 mg/LH 2 O 2 结合可以在反应20分钟后将残余溶解的2-MIB降解近100% 。基于最佳剂量,0.6 m 3/h中试系统,包括预臭氧化、混凝沉淀、砂滤和后过氧酮工艺,连续运行14天,发现所提出的工艺可以有效稳定地去除丝状蓝藻和2-MIB。