A major cleanup for starting anew: Bio-inspired Breslow-type enolates, which mimic thiamine derivatives, are far better reducing agents than previously considered. The reevaluation of the redox ability of these key intermediates refutes established misconceptions and sheds a new light on radical processes involving N-heterocyclic carbene catalysis.

中文翻译：

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Breslow 型衍生物的还原能力的批判性评估及其对卡宾催化自由基反应的影响**

重新开始的主要清理：仿生硫胺素衍生物的仿生 Breslow 型烯醇化物是比以前考虑的更好的还原剂。对这些关键中间体的氧化还原能力的重新评估驳斥了既定的误解，并为涉及 N-杂环卡宾催化的自由基过程提供了新的思路。