Syntheses of Optically Active V-Shaped Molecules: Relationship Between their Chiroptical Properties and the Orientation of the Stacked π-Electron System,European Journal of Organic Chemistry

当前位置： X-MOL 学术 › Eur. J. Org. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Syntheses of Optically Active V-Shaped Molecules: Relationship Between their Chiroptical Properties and the Orientation of the Stacked π-Electron System
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-10-13 , DOI: 10.1002/ejoc.202101119
Ryo Asakawa ₁ , Daiki Tabata ₂ , Nanami Miki ₂ , Motoki Tsuchiya ₂ , Ryo Inoue ₂ , Yasuhiro Morisaki ₃

Affiliation

Two kinds of optically active V-shaped molecules were synthesized from enantiopure [2.2]paracyclophane as chiral building blocks. Although the two molecules consisted of the same π-electron system, the orientations of the stacked π-electron systems were different. Circularly polarized luminescence behaviors could be controlled by adjusting their orientation.