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Isobaric Vapor–Liquid Equilibrium for the Binary Systems of 2-Phenylethanol + 2-Ethylphenol, 1-Phenyl-2-propanol + 2-Ethylphenol, 2-Phenylethanol + 1-Phenyl-2-propanol and 2-Phenyl-1-propanol + 2-Ethylphenol under 101.3 kPa
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2021-10-13 , DOI: 10.1021/acs.jced.1c00500
Qing Yi 1 , Wei-Peng Chen 1 , Xiang-yang Zhang 1 , Yan-Yang Wu 1 , Bin Wu 1 , Kui Chen 1 , Li-Jun Ji 1
Affiliation  

The isobaric vapor–liquid equilibrium (VLE) data of 2-phenylethanol (2-PE) + 2-ethylphenol (2-EP), 1-phenyl-2-propanol (1,2-PP) + 2-ethylphenol (2-EP), 2-phenylethanol (2-PE) + 1-phenyl-2-propanol (1,2-PP) and 2-phenyl-1-propanol (2,1-PP) + 2-ethylphenol (2-EP) were measured by a modified Rose type still under 101.3 kPa. Both the Fredenslund test and Redlich–Kister area test were employed to verify the consistency of the experimental data. Besides, the experimental isobaric VLE data were correlated by Wilson, nonrandom two-liquid, and universal quasi-chemical models, and the corresponding parameters were obtained accordingly. All three models showed good agreement with the experimental data, and among which the Wilson model performed slightly better than the others.

中文翻译:

2-苯基乙醇 + 2-乙基苯酚、1-苯基-2-丙醇 + 2-乙基苯酚、2-苯基乙醇 + 1-苯基-2-丙醇和 2-苯基-1-丙醇 + 二元系统的等压蒸汽-液体平衡101.3 kPa以下的2-乙基苯酚

2-苯基乙醇 (2-PE) + 2-乙基苯酚 (2-EP)、1-苯基-2-丙醇 (1,2-PP) + 2-乙基苯酚 (2- EP)、2-苯基乙醇 (2-PE) + 1-苯基-2-丙醇 (1,2-PP) 和 2-苯基-1-丙醇 (2,1-PP) + 2-乙基苯酚 (2-EP)由仍低于 101.3 kPa 的改良 Rose 型进行测量。Fredenslund检验和Redlich-Kister面积检验均用于验证实验数据的一致性。此外,实验等压VLE数据通过Wilson模型、非随机二液模型和通用准化学模型进行关联,并据此得到相应的参数。三个模型均与实验数据显示出良好的一致性,其中威尔逊模型的表现略好于其他模型。
更新日期:2021-12-09
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