The growing amounts of plastic and biomass wastes have become a global problem challenging the environmental sustainability. In this regard, waste to energy technologies has gained more importance to convert waste inventory into useful energy and value added products. In this study, pyrolysis characteristics of a textile industry waste (recycled polyester fabric, RPF) and an agricultural waste (olive residue, OR) and their (1/1 wt.%) blend are investigated via thermo-gravimetric analysis (TGA) method. Thermal degradation were examined at heating rates of 10, 30 and 50°C min^-1 heated to 1000C with 100 mL min^-1 flow of nitrogen. Kinetic analysis of pyrolysis has been performed with Flynn-Wall-Ozawa (FWO) method. Experimental and theoretical TGA profiles compared and some synergistic interactions have obtained during co-pyrolysis. The activation energies are determined as 254.22, 203.22, 231.72 kJmol^-1 for RPF, OR and RPF/OR blend, respectively. The results of kinetics analysis and evaluation of the thermodynamic parameters (activation energy, enthalpy, Gibb’s free energy and entropy) have shown that co-pyrolysis of OR and RPF is promising alternative for sustainable bioenergy production.

中文翻译：

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橄榄渣/再生聚酯热解动力学和热力学行为评价

越来越多的塑料和生物质废物已成为挑战环境可持续性的全球性问题。在这方面，废物转化为能源技术在将废物库存转化为有用的能源和增值产品方面变得更加重要。在这项研究中，通过热重分析 (TGA) 方法研究了纺织工业废物（再生聚酯织物，RPF）和农业废物（橄榄残渣，OR）及其（1/1 wt.%）混合物的热解特性. 在10、30和 50°C min ^-1加热至 1000C 的加热速率下检查热降解，100 mL min ^-1氮气流量。热解动力学分析已使用 Flynn-Wall-Ozawa (FWO) 方法进行。比较实验和理论 TGA 曲线，并在共热解过程中获得了一些协同相互作用。RPF、OR 和 RPF/OR 混合物的活化能分别确定为 254.22、203.22、231.72 kJmol ^-1。动力学分析和热力学参数（活化能、焓、吉布斯自由能和熵）的评估结果表明，OR 和 RPF 的共热解是可持续生物能源生产的有希望的替代方案。