First-Row d-Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes,Chemical Reviews

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First-Row d-Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes
Chemical Reviews ( IF 51.4 ) Pub Date : 2021-10-07 , DOI: 10.1021/acs.chemrev.1c00255
Shubhankar Kumar Bose ₁ , Lujia Mao ₂ , Laura Kuehn ₃ , Udo Radius ₃ , Jan Nekvinda ₄ , Webster L Santos ₄ , Stephen A Westcott ₅ , Patrick G Steel ₆ , Todd B Marder ₃

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Organoboron reagents represent a unique class of compounds because of their utility in modern synthetic organic chemistry, often affording unprecedented reactivity. The transformation of the carbon–boron bond into a carbon–X (X = C, N, and O) bond in a stereocontrolled fashion has become invaluable in medicinal chemistry, agrochemistry, and natural products chemistry as well as materials science. Over the past decade, first-row d-block transition metals have become increasingly widely used as catalysts for the formation of a carbon–boron bond, a transformation traditionally catalyzed by expensive precious metals. This recent focus on alternative transition metals has enabled growth in fundamental methods in organoboron chemistry. This review surveys the current state-of-the-art in the use of first-row d-block element-based catalysts for the formation of carbon–boron bonds.

中文翻译：

第一行 d-block 元素催化的碳-硼键形成及相关过程

有机硼试剂代表了一类独特的化合物，因为它们在现代合成有机化学中的实用性，通常提供前所未有的反应性。以立体控制的方式将碳-硼键转变为碳-X（X = C、N 和 O）键在药物化学、农业化学、天然产物化学以及材料科学中具有不可估量的价值。在过去十年中，第一排 d 区过渡金属越来越广泛地用作形成碳 - 硼键的催化剂，这种转变传统上由昂贵的贵金属催化。最近对替代过渡金属的关注促进了有机硼化学基础方法的发展。这篇评论调查了当前最先进的技术在使用第一排 d 区元素基催化剂形成碳 - 硼键时。

更新日期：2021-11-10

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