当前位置: X-MOL 学术Eur. J. Org. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Ruthenium-Catalyzed Sulfoalkenylation of Acetanilides and Dual-Use of the Catalyst Directing Group
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-10-07 , DOI: 10.1002/ejoc.202101216
Patrick Sand 1 , Bernd Schmidt 2
Affiliation  

Through Ruthenium-catalysis, some limitations of Pd-catalyzed C−H-activation for the ortho-alkenylation of acetamides with vinylsulfones and vinylsulfonamides can be overcome. The products are useful starting points for a short synthesis of sulfonylated pyrroloquinolines.
image


中文翻译:

钌催化乙酰苯胺的磺基烯基化和催化剂导向基团的双重用途

通过钌催化,可以克服 Pd 催化的 C-H 活化对乙酰胺与乙烯基砜和乙烯基磺酰胺的邻位烯基化的一些限制。这些产品是磺酰化吡咯并喹啉的短程合成的有用起点。
图片
更新日期:2021-10-22
down
wechat
bug