Department of Physical and Chemical Sciences Università degli Studi dell'Aquila Via Vetoio 67100 L'Aquila Italy
Department of Biotechnological and Applied Clinical Sciences Università degli Studi dell'Aquila Via Vetoio 67100 L'Aquila Italy
Department of Life Sciences Università degli Studi di Modena e Reggio Emilia Via G. Campi 103 41125 Modena Italy
Department of Chemical and Pharmaceutical Sciences Università degli Studi di Trieste Via Giorgieri 1 34127 Trieste Italy
Unit of Trieste National Interuniversity Consortium of Materials Science and Technology (INSTM) Via Giorgieri 1 34127 Trieste Italy
Istituto per la Sintesi Organica e la Fotoreattività Consiglio Nazionale delle Ricerche Via P. Gobetti 101 40129 Bologna Italy
The Cover Feature shows the catalytic activity exerted by a minimalistic peptide behaving as an organocatalyst in a Michael addition. A supramolecular arrangement on the catalyst in fibrils showed to remarkably improve the TOF of the catalyst. The aldehyde donors and nitroalkenes acceptors are represented in the top left corner and are largely converted to the adduct as the reaction proceeds, towards the bottom right. Across the image the self-assembled fibrils of a minimalistic tripeptide, catalyzing the reaction, are shown; the tripeptide is shown in detail, colored green, for one of the fibrils. Image credit: Nicola De Mitri. More information can be found in the Communication by A. Carlone et al.
中文翻译：
封面特征：通过自组装最小结构加速不对称有机催化（Eur. J. Org. Chem. 39/2021）
Cover Feature显示了在迈克尔加成中充当有机催化剂的极简肽发挥的催化活性。原纤维中催化剂上的超分子排列显示出显着提高了催化剂的TOF。醛供体和硝基烯烃受体显示在左上角，随着反应的进行，大部分转化为加合物，朝向右下角。整个图像显示了催化反应的极简三肽的自组装原纤维；详细显示了其中一根原纤维的三肽，颜色为绿色。图片来源：Nicola De Mitri。更多信息可以在 A. Carlone 等人的通讯中找到。
京公网安备 11010802027423号