Conformational Control of a Metallo-Supramolecular Cage via the Dissymmetrical Modulation of Ligands,Angewandte Chemie International Edition

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Conformational Control of a Metallo-Supramolecular Cage via the Dissymmetrical Modulation of Ligands
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-29 , DOI: 10.1002/anie.202111430
Hao Yu ₁ , Jiaqi Li ₁ , Chuan Shan ₂ , Tong Lu ₁ , Xin Jiang ₁ , Junjuan Shi ₁ , Lukasz Wojtas ₂ , Houyu Zhang ₁ , Ming Wang ₁

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Generally, self-assembly of dissymmetrical ligands can generate a series of isomers with similar thermodynamic stability. In this work, the conformation in the self-assembly process can be precisely controlled via the increase in ligand dissymmetry. Finally, only the cis-isomer was obtained. This strategy offered an avenue for designing metallo-supramolecular architectures based on dissymmetrical organic ligands.