Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions,Chemistry - A European Journal

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Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2021-09-27 , DOI: 10.1002/chem.202103096
Grégoire Sieg ₁ , Quentin Pessemesse _{2,

3} , Sascha Reith ₁ , Stefan Yelin ₄ , Christian Limberg ₄ , Dominik Munz _{3,

5} , C Gunnar Werncke ₁

Affiliation

Herein, the isolation of ketyl, and more importantly ketiminyl and aldiminyl radical anions coordinated to cobalt- and iron is presented. Insights into the electronic structure of these unusual metal bound radical anions is provided by various analytical methods as well as by a detailed computational analysis. The metal bound radical anions are very reactive and facilitate the activation of intra- and intermolecular C−H bonds.

中文翻译：

钴和铁稳定的酮基、酮亚胺基和醛二亚胺基阴离子

在此，提出了与钴和铁配位的酮基，更重要的是酮亚胺基和醛亚胺基自由基阴离子的分离。通过各种分析方法以及详细的计算分析，可以深入了解这些不寻常的金属结合自由基阴离子的电子结构。金属结合的自由基阴离子非常活泼，有利于分子内和分子间 C−H 键的活化。

更新日期：2021-12-02

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