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Development of green and low-cost chiral oxidants for asymmetric catalytic hydroxylation of enals
Green Synthesis and Catalysis ( IF 8.2 ) Pub Date : 2021-8-27 , DOI: 10.1016/j.gresc.2021.05.002 Xiaoqun Yang , Hongling Wang , Zhichao Jin , Yonggui Robin Chi
Green Synthesis and Catalysis ( IF 8.2 ) Pub Date : 2021-8-27 , DOI: 10.1016/j.gresc.2021.05.002 Xiaoqun Yang , Hongling Wang , Zhichao Jin , Yonggui Robin Chi
A new type of chiral oxidants are developed and successfully applied in the
asymmetric -hydroxylation of enals under the catalysis of an inexpensive
achiral NHC catalyst. This type of chiral oxidants can be easily prepared
from the low-cost starting materials of substituted benzoic acids and chiral
prolinols through simple dehydrative amidation reactions
中文翻译:
用于烯醛不对称催化羟基化的绿色低成本手性氧化剂的开发
开发了一种新型手性氧化剂,并在廉价的非手性 NHC 催化剂的催化下成功应用于烯醛的不对称羟基化反应。这种手性氧化剂可以由取代苯甲酸和手性脯氨醇的低成本原料通过简单的脱水酰胺化反应轻松制备
更新日期:2021-09-29
中文翻译:
用于烯醛不对称催化羟基化的绿色低成本手性氧化剂的开发
开发了一种新型手性氧化剂,并在廉价的非手性 NHC 催化剂的催化下成功应用于烯醛的不对称羟基化反应。这种手性氧化剂可以由取代苯甲酸和手性脯氨醇的低成本原料通过简单的脱水酰胺化反应轻松制备