Cement and Concrete Research ( IF 10.9 ) Pub Date : 2021-09-24 , DOI: 10.1016/j.cemconres.2021.106608 Céline Cau Dit Coumes 1 , Angélique Rousselet 2 , Biwan Xu 1 , Cyrille Albert Mercier 3 , Sandrine Gauffinet 2
In this study, the influence of aluminum nitrate on the hydration process of magnesium potassium phosphate (MKP) cement was investigated experimentally and through thermodynamic modelling using diluted systems with Mg/PO4 molar ratio and water-to-cement ratio of 1 and 100 respectively. Three processes contributed to retard cement hydration: the acidic nature of aluminum nitrate which reduced the initial pH of the solution by two units, the early precipitation of a taranakite-like amorphous potassium aluminophosphate, which reduced the aqueous phosphate and potassium concentrations, and a salt effect due to the presence of soluble nitrate. Precipitation of potassium-containing magnesium phosphate hydrates, like Mg2KH(PO4)2⋅15H2O and K-struvite, was prohibited, whereas precipitation of newberyite and cattiite was delayed. Furthermore, the modelled phase development with ongoing cement hydration agreed rather well with the experimental findings.
中文翻译:
硝酸铝作为磷酸镁钾水泥缓凝剂的研究:稀释悬浮液的作用机制
在本研究中,使用 Mg/PO 4摩尔比和水灰比分别为 1 和 100 的稀释体系,通过实验和热力学模型研究了硝酸铝对磷酸镁钾 (MKP) 水泥水化过程的影响. 三个过程有助于延缓水泥水化:硝酸铝的酸性使溶液的初始 pH 值降低两个单位,早期沉淀类似塔拉纳克石的无定形磷酸铝钾,降低了磷酸盐和钾的浓度,以及盐由于可溶性硝酸盐的存在。含钾磷酸镁水合物的沉淀,如 Mg 2 KH(PO 4 ) 2 ⋅15H2 O 和 K-鸟粪石被禁止,而新辉石和钙钛矿的沉淀被延迟。此外,模拟的水泥水化相发展与实验结果非常吻合。