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Investigation of aluminum nitrate as a set retarder of magnesium potassium phosphate cement: Mechanisms involved in diluted suspension
Cement and Concrete Research ( IF 10.9 ) Pub Date : 2021-09-24 , DOI: 10.1016/j.cemconres.2021.106608
Céline Cau Dit Coumes 1 , Angélique Rousselet 2 , Biwan Xu 1 , Cyrille Albert Mercier 3 , Sandrine Gauffinet 2
Affiliation  

In this study, the influence of aluminum nitrate on the hydration process of magnesium potassium phosphate (MKP) cement was investigated experimentally and through thermodynamic modelling using diluted systems with Mg/PO4 molar ratio and water-to-cement ratio of 1 and 100 respectively. Three processes contributed to retard cement hydration: the acidic nature of aluminum nitrate which reduced the initial pH of the solution by two units, the early precipitation of a taranakite-like amorphous potassium aluminophosphate, which reduced the aqueous phosphate and potassium concentrations, and a salt effect due to the presence of soluble nitrate. Precipitation of potassium-containing magnesium phosphate hydrates, like Mg2KH(PO4)2⋅15H2O and K-struvite, was prohibited, whereas precipitation of newberyite and cattiite was delayed. Furthermore, the modelled phase development with ongoing cement hydration agreed rather well with the experimental findings.



中文翻译:

硝酸铝作为磷酸镁钾水泥缓凝剂的研究:稀释悬浮液的作用机制

在本研究中,使用 Mg/PO 4摩尔比和水灰比分别为 1 和 100 的稀释体​​系,通过实验和热力学模型研究了硝酸铝对磷酸镁钾 (MKP) 水泥水化过程的影响. 三个过程有助于延缓水泥水化:硝酸铝的酸性使溶液的初始 pH 值降低两个单位,早期沉淀类似塔拉纳克石的无定形磷酸铝钾,降低了磷酸盐和钾的浓度,以及盐由于可溶性硝酸盐的存在。含钾磷酸镁水合物的沉淀,如 Mg 2 KH(PO 4 ) 2 ⋅15H2 O 和 K-鸟粪石被禁止,而新辉石和钙钛矿的沉淀被延迟。此外,模拟的水泥水化相发展与实验结果非常吻合。

更新日期:2021-09-24
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