A soluble iron(II)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides,Chemical Communications

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A soluble iron(II)-phthalocyanine-catalyzed intramolecular C(sp3)–H amination with alkyl azides
Chemical Communications ( IF 4.9 ) Pub Date : 2021-09-23 , DOI: 10.1039/d1cc04573c
Tingjie You _{1,

2} , Si-Hao Zeng _{1,

3} , Jianqiang Fan ₁ , Liangliang Wu _{1,

2} , Fangyuan Kang ₁ , Yungen Liu ₁ , Chi-Ming Che _{1,

2,

3,

4,

5}

Affiliation

Herein, we describe a soluble iron(II)-phthalocyanine, [Fe^II(^tBu₄Pc)(py)₂] (Pc = phthalocyaninato(2–)), as an effective catalyst in intramolecular C(sp³)–H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.

中文翻译：

可溶性铁 (II)-酞菁催化的分子内 C(sp3)-H 胺化与烷基叠氮化物

在此，我们描述了一种可溶性铁 ( II )-酞菁 [Fe ^II ( ^t Bu ₄ Pc)(py) ₂ ] (Pc = phthalocyaninato(2-))，作为分子内 C(sp ³ )-H的有效催化剂键胺化，以烷基叠氮化物为氮源，以中等至优异的产率提供胺化产物，底物范围广泛。

更新日期：2021-09-23

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