Oxidation of Dithia Compounds: Comparative Experimental and Theoretical Studies on 1,3-Bis(methylthio)propane, Bis(methylthio)methane, and meso-4,6-Dimethyl-1,3-dithiane,European Journal of Organic Chemistry

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Oxidation of Dithia Compounds: Comparative Experimental and Theoretical Studies on 1,3-Bis(methylthio)propane, Bis(methylthio)methane, and meso-4,6-Dimethyl-1,3-dithiane
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-09-23 , DOI: 10.1002/ejoc.202100940
Victorino Vallejos González ₁ , Joachim Podlech ₂

Affiliation

The mutual influence of the sulfur groups in 1,3-dithia compounds is especially obvious in conformationally constrained 1,3-dithianes. Oxidations with different oxidants are investigated experimentally by NMR spectroscopical analysis and by calculation of activation barriers and stereoelectronic effects by using quantum chemical methods.

中文翻译：

Dithia 化合物的氧化：1,3-双（甲硫基）丙烷、双（甲硫基）甲烷和内消旋 4,6-二甲基-1,3-二噻烷的比较实验和理论研究

1,3-二硫杂化合物中硫基的相互影响在构象受限的1,3-二噻烷中尤为明显。通过核磁共振光谱分析和使用量子化学方法计算激活势垒和立体电子效应，对不同氧化剂的氧化进行了实验研究。

更新日期：2021-10-19

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