Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Bromides and Chlorosilanes,Organic Letters

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Nickel-Catalyzed Reductive Cross-Coupling of Alkyl Bromides and Chlorosilanes
Organic Letters ( IF 4.9 ) Pub Date : 2021-09-22 , DOI: 10.1021/acs.orglett.1c02887
Mimi Xing ₁ , Huanhuan Cui ₁ , Chun Zhang _{1,

2}

Affiliation

A novel nickel-catalyzed highly selective reductive cross-coupling of alkyl bromides and chlorosilanes to construct the C–Si bond has been developed. Under benign reaction conditions, a series of structurally interesting organosilanes can be accessed without Ni-catalyzed isomerization. The utility of this chemistry is illustrated by further transformations of the product. Moreover, the radical mechanism of the reaction is illustrated by control experiments.

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