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Fabrication of Cu-WO3-functionalised multiwalled carbon nanotubes composite film electrode by direct deposition for sensing application
Thin Solid Films ( IF 2.0 ) Pub Date : 2021-09-23 , DOI: 10.1016/j.tsf.2021.138940
M. Reshma 1 , R. Manu 1
Affiliation  

Development of nano composite film electrodes have been widely researched for its application as sensors, pseudo capacitors and negative electrodes. Different types of metal oxides, nano materials and various deposition techniques were concomitantly employed for fabrication of this type of electrodes. In the present work electroless deposition technique was applied for formation of copper seed layer over flexible poly ethylene substrate and further electrodeposition of WO3-functionalized multi walled carbon nanotube (fMWCNT) on to copper seed layer. Stable conducting films with uniform morphology of WO3-fMWCNT nano composite was formed over flexible copper substrate. The composite film possessed good electrochemical stability as revealed from various electrochemical analysis. The Cu-WO3-fMWCNT films were used as sensor for qualitative analysis of lubricant oils subjected to aging process under controlled conditions. The developed film electrode give good response curve in the impedance spectroscopy technique during the analysis of fresh and aged lubricant oil Different techniques such as X-ray Powder Diffraction, Scanning Electron Microscopy, Energy Dispersive X-Ray analysis with mapping pattern and Fourier Transform Infrared technique was used for characterization of the hybrid film electrode.



中文翻译:

通过直接沉积制备用于传感应用的 Cu-WO3 功能化多壁碳纳米管复合膜电极

纳米复合膜电极的开发因其作为传感器、伪电容器和负极的应用而得到广泛研究。不同类型的金属氧化物、纳米材料和各种沉积技术同时用​​于制造这种类型的电极。在目前的工作中,无电沉积技术被应用于在柔性聚乙烯衬底上形成铜种子层,并进一步将 WO 3功能化的多壁碳纳米管 (fMWCNT)电沉积到铜种子层上。具有均匀WO 3形态的稳定导电薄膜-fMWCNT 纳米复合材料在柔性铜基板上形成。各种电化学分析表明复合膜具有良好的电化学稳定性。Cu-WO 3 -fMWCNT薄膜用作传感器,用于在受控条件下对经受老化过程的润滑油进行定性分析。开发的薄膜电极在分析新鲜和老化的润滑油过程中在阻抗谱技术中提供了良好的响应曲线 不同的技术,如 X 射线粉末衍射、扫描电子显微镜、具有映射模式的能量色散 X 射线分析和傅里叶变换红外技术用于表征混合膜电极。

更新日期:2021-09-29
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