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Green synthesis of bis pyrazole-triazole and azo-linked triazole hybrids using an efficient and novel cobalt nanocatalyst
Reaction Kinetics, Mechanisms and Catalysis ( IF 1.7 ) Pub Date : 2021-09-22 , DOI: 10.1007/s11144-021-02076-8
Iman Rezaei 1 , Manouchehr Mamaghani 1
Affiliation  

In the current work, new cobalt incorporated fluorapatite encapsulated iron oxide nanocatalyst (γ-Fe2O3@FAp@Co) was prepared and characterized by using FT-IR, XRD, SEM, TEM, VSM, and EDX techniques. The catalyst was utilized in the synthesis of novel derivatives of symmetric bis-triazoles by the reaction of various aldehydes and butane-1,4-diyl bis(hydrazinecarbimidothioate) in ethanol at room temperature. γ-Fe2O3@FAp@Co was easily removed from the reaction mixture using an external magnet and was used several times without decreased catalytic properties. This method provided a novel approach for the green synthesis of bis-triazoles in excellent yield (88–95%) and reasonable reaction time (60–80 min). The structures of prepared compounds were confirmed by analytical methods.



中文翻译:

使用高效新型钴纳米催化剂绿色合成双吡唑-三唑和偶氮连接的三唑杂化物

在目前的工作中,使用 FT-IR、XRD、SEM、TEM、VSM 和 EDX 技术制备并表征了新的掺钴氟磷灰石包封的氧化铁纳米催化剂(γ-Fe 2 O 3 @FAp@Co)。该催化剂用于在室温下通过各种醛和丁烷-1,4-二基双(肼碳亚氨基硫酸酯)在乙醇中的反应合成对称双三唑的新型衍生物。γ-Fe 2 O 3@FAp@Co 很容易使用外部磁铁从反应混合物中去除,并且可以多次使用而不会降低催化性能。该方法为以优异的收率(88-95%)和合理的反应时间(60-80 分钟)绿色合成双三唑提供了一种新方法。制备的化合物的结构通过分析方法得到证实。

更新日期:2021-09-23
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