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Poly[N-(2-chloroprop-2-en-1-yl)aniline]s: synthesis, polymer analogous reaction, and physicochemical properties
Polymer Chemistry ( IF 4.1 ) Pub Date : 2021-09-13 , DOI: 10.1039/d1py00940k Akhat G. Mustafin 1 , Lyaysan R. Latypova 1 , Anastasiia N. Andriianova 1 , Gulsum S. Usmanova 1
Polymer Chemistry ( IF 4.1 ) Pub Date : 2021-09-13 , DOI: 10.1039/d1py00940k Akhat G. Mustafin 1 , Lyaysan R. Latypova 1 , Anastasiia N. Andriianova 1 , Gulsum S. Usmanova 1
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A series of new soluble N-substituted poly(β-haloallylaniline)s, namely poly[N-(2-chloroprop-2-en-1-yl)aniline] (NPC), poly[N-(2-chloroprop-2-en-1-yl)-2-methylaniline] (NPT) and poly[N-(2-chloroprop-2-en-1-yl)-2-methoxyaniline] (NPA), were synthesized by oxidative polymerization in 1 M HCl medium using (NH4)2S2O8 as the oxidant. Based on these polymers and polyphosphoric acid, various functionalized polyindoles of a new type were obtained in high yields. All the polymers obtained were characterized by 1H and 13C NMR, IR and UV-spectroscopy, elemental analysis, scanning electron microscopy (SEM), and thermal gravimetric analysis (TGA). The optical properties were studied, and the indole polymers were found to exhibit photoconductivity. Comparative analysis of spectral data and physicochemical properties indicates that intramolecular cyclization of the polyaniline derivatives occurs successfully.
中文翻译：
聚[N-(2-chloroprop-2-en-1-yl)aniline]s：合成、聚合物类似反应和物理化学性质
一系列新型可溶性N-取代聚（β-卤代烯丙胺），即聚[ N- (2-氯丙-2-烯-1-基)苯胺](NPC)、聚[ N- (2-氯丙-2) -en-1-yl)-2-methylaniline] (NPT) 和聚 [ N -(2-chloroprop-2-en-1-yl)-2-甲氧基苯胺] (NPA)，在 1 M 中通过氧化聚合合成使用 (NH 4 ) 2 S 2 O 8作为氧化剂的HCl 介质。基于这些聚合物和多聚磷酸，以高产率获得了各种新型官能化聚吲哚。获得的所有聚合物的特征在于1 H 和13C NMR、IR 和 UV 光谱、元素分析、扫描电子显微镜 (SEM) 和热重分析 (TGA)。研究了光学性质，发现吲哚聚合物表现出光电导性。光谱数据和理化性质的比较分析表明聚苯胺衍生物的分子内环化成功发生。
更新日期：2021-09-23
中文翻译：
聚[N-(2-chloroprop-2-en-1-yl)aniline]s：合成、聚合物类似反应和物理化学性质
一系列新型可溶性N-取代聚（β-卤代烯丙胺），即聚[ N- (2-氯丙-2-烯-1-基)苯胺](NPC)、聚[ N- (2-氯丙-2) -en-1-yl)-2-methylaniline] (NPT) 和聚 [ N -(2-chloroprop-2-en-1-yl)-2-甲氧基苯胺] (NPA)，在 1 M 中通过氧化聚合合成使用 (NH 4 ) 2 S 2 O 8作为氧化剂的HCl 介质。基于这些聚合物和多聚磷酸，以高产率获得了各种新型官能化聚吲哚。获得的所有聚合物的特征在于1 H 和13C NMR、IR 和 UV 光谱、元素分析、扫描电子显微镜 (SEM) 和热重分析 (TGA)。研究了光学性质，发现吲哚聚合物表现出光电导性。光谱数据和理化性质的比较分析表明聚苯胺衍生物的分子内环化成功发生。
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