Enzymes use adaptive catalytic pocket to accelerate catalysis. Recently published in Nature Catalysis, Zhong and coworkers have translated this functionality into a MOF with a Cu-Ni active site in which the Cu-Ni distance changes to stabilize intermediates along the CO₂ to CH₄ pathway and give rise to exceptional catalytic selectivity.

中文翻译：

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适应性框架 CO2 催化

酶使用适应性催化袋来加速催化。最近发表在Nature Catalysis 上，Zhong 及其同事已将此功能转化为具有 Cu-Ni 活性位点的 MOF，其中 Cu-Ni 距离发生变化以稳定沿 CO ₂到 CH ₄途径的中间体，并产生出色的催化选择性。