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Deciphering and Suppressing Over-Oxidized Nitrogen in Nickel-Catalyzed Urea Electrolysis
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-23 , DOI: 10.1002/anie.202107886
Jianan Li 1 , Jili Li 2 , Tao Liu 2 , Lin Chen 2 , Yefei Li 2, 3 , Hualin Wang 1 , Xiurong Chen 1 , Ming Gong 2 , Zhi-Pan Liu 2, 3 , Xuejing Yang 1
Affiliation  

A systematic investigation of the nitrogen network during the nickel-catalyzed urea oxidation reaction was carefully performed. It revealed a dominant NO2 production rather than innocuous N2 present on various nickel-based catalysts. Accordingly, polymer-surface modification was put forward to increase the efficiency of harmless N2 products.
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中文翻译:

镍催化尿素电解中过氧化氮的破译和抑制

对镍催化尿素氧化反应过程中的氮网络进行了系统研究。它揭示了在各种镍基催化剂上存在主要的NO 2 -生成而不是无害的N 2。因此,提出了聚合物表面改性以提高无害N 2产品的效率。
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更新日期:2021-09-23
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