Abstract

Activation of B–H groups of polyhedral boron hydrides (boranes and carboranes) is one of the most actively developing areas of boron chemistry and is of considerable interest for specialists in organic chemistry, organometallic catalysis, and coordination chemistry. This review summarizes the data on the functional group directed B–H activation reactions of polyhedral boron hydrides by transition metal complexes, beginning from the early 1980s and ending with the most recent advances in this area. The formation of complexes of transition metals with M···H–B and M–B bonds and their use in the synthesis of various organic derivatives of (car)boranes are considered.

中文翻译：

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过渡金属配合物对多面体氢化硼的官能团定向 B-H 活化（综述）

摘要

多面体硼氢化物（硼烷和碳硼烷）的 B-H 基团的活化是硼化学发展最活跃的领域之一，并且对有机化学、有机金属催化和配位化学方面的专家非常感兴趣。这篇综述总结了从 1980 年代初开始，以该领域的最新进展结束的过渡金属络合物对多面体氢化硼进行的官能团定向 B-H 活化反应的数据。过渡金属与 M···H-B 和 M-B 键的配合物的形成及其在（碳）硼烷的各种有机衍生物的合成中的应用被考虑。