Efficient catalysis is essential from a green chemistry perspective. Porous organic polymers (POPs) have recently emerged as highly effective materials for catalytic applications. POPs possess controllable compositions and functionalities, high surface areas and can be very stable. In this review we focus on the application of POPs as metal free heterogeneous organocatalysts, a booming field in green chemistry. Acid, base, combined acid–base and hydrogen bonding catalysis are addressed. In addition, chiral catalysis and CO₂ utilization with POPs are discussed. The aim is to provide a comprehensive overview of the field, exploring all different types of POPs as metal free catalysts. Special attention is given to the synthesis conditions to provide the reader with more insight into the construction of these types of materials.

中文翻译：

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作为无金属多相有机催化剂的多孔有机聚合物

从绿色化学的角度来看，高效的催化是必不可少的。多孔有机聚合物 (POPs) 最近已成为催化应用的高效材料。持久性有机污染物具有可控的成分和功能、高表面积并且非常稳定。在这篇综述中，我们重点关注持久性有机污染物作为无金属多相有机催化剂的应用，这是绿色化学中一个蓬勃发展的领域。酸、碱、酸碱结合和氢键催化都得到了解决。此外，手性催化和 CO ₂讨论了 POPs 的利用。目的是提供该领域的全面概述，探索作为无金属催化剂的所有不同类型的持久性有机污染物。对合成条件给予了特别关注，以使读者更深入地了解这些类型材料的构造。