Grinding the Cubes─Multigram Solid-State Synthesis of Silsesquioxane Amic Acids,ACS Sustainable Chemistry & Engineering

当前位置： X-MOL 学术 › ACS Sustain. Chem. Eng. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Grinding the Cubes─Multigram Solid-State Synthesis of Silsesquioxane Amic Acids
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2021-09-21 , DOI: 10.1021/acssuschemeng.1c05188
Barbara Kaczmarek ₁ , Mariusz Szołyga ₂ , Dawid Fra̧ckowiak ₃

Affiliation

For the first time, ball milling is used in the functionalization of silsesquioxanes. The solid-state nucleophilic addition of aminopropylisobutyl POSS to cyclic anhydrides leads to silsesquioxane amic acids in virtually quantitative yields without the use of a solvent. The reactions are easily scalable and can be adopted to multigram quantities.

中文翻译：