Ultrafiltration membranes have shown remarkable potential in the purification of textile printing and dyeing wastewater. However, ultrafiltration membranes have some disadvantages in wastewater treatment, such as membrane fouling and trade-off effect. Hence, a novel polysulfone (PSF)-reduced graphene oxide (rGO)-zinc oxide (ZnO) composite conductive ultrafiltration membrane was prepared via the simple and green method. The combination of conductive ultrafiltration membrane and external electric field could treat dye wastewater. The conductive rGO/ZnO/PSF membranes have high water flux (296 L m⁻² h⁻¹ Bar⁻¹) and favorable removal rates (>90%) for Congo Red (CR), Methyl Orange (MO), and Methylene Blue (MB). Besides, rGO/ZnO/PSF membrane also showed excellent antifouling ability, which had a flux recovery rate of 93% after filtration of bovine serum albumin (BSA) under applied electric field. Due to the electrocatalytic cleaning, rGO/ZnO/PSF membrane exhibited a 90% flux recovery after filtering the dye. The rGO/ZnO/PSF membrane has good separation efficiency, electrocatalytic stability, and fouling resistance, and can effectively solve the purification of textile printing and dyeing.

超滤膜在纺织印染废水的净化方面显示出巨大的潜力。然而，超滤膜在废水处理中存在一些缺点，例如膜污染和权衡效应。因此，通过简单、绿色的方法制备了一种新型聚砜（PSF）-还原氧化石墨烯（rGO）-氧化锌（ZnO）复合导电超滤膜。导电超滤膜与外电场结合可处理染料废水。导电 rGO/ZnO/PSF 膜具有高水通量 (296 L m ^-2  h ^-1 Bar ^-1) 和对刚果红 (CR)、甲基橙 (MO) 和亚甲蓝 (MB) 有利的去除率 (>90%)。此外，rGO/ZnO/PSF膜还表现出优异的防污能力，在外加电场作用下过滤牛血清白蛋白（BSA）后通量回收率为93%。由于电催化清洗，rGO/ZnO/PSF 膜在过滤染料后表现出 90% 的通量恢复。rGO/ZnO/PSF膜具有良好的分离效率、电催化稳定性和抗污染性，能有效解决纺织印染的净化问题。