Cover Feature: Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis. (Z. Anorg. Allg. Chem. 18/2021),Zeitschrift für anorganische und allgemeine Chemie

当前位置： X-MOL 学术 › Z. Anorg. Allg. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Cover Feature: Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis. (Z. Anorg. Allg. Chem. 18/2021)
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2021-09-21 , DOI: 10.1002/zaac.202100288
Matthias Kotsch ₁ , Yurii Prots ₁ , Alim Ormeci ₁ , Anatoliy Senyshyn ₂ , Miroslav Kohout ₁ , Yuri Grin ₁

Affiliation

This cover picture shows the unique bell-like [Ga₅] cluster and its corresponding ELI-D maxima, in front of a drawing of an old school bell. First observed in the related compound Eu₃Li₅Ga₅ these clusters are the first and only known galliumclusters to be nonconvex, which makes an investigation of the intra cluster bonding of particular interest. Initially hindered by the presence of europium, an application of the electron localizability approach (ELI-D) became possible with Sr₃Li₅Ga₅ due to the absence of f electrons. The resulting insights into the bonding situation are described in great detail in our article 202100147.

中文翻译：

封面特征：Sr3Li5Ga5 中的类钟形 [Ga5] 簇：合成、晶体结构和键合分析。(Z. Anorg. Allg. Chem. 18/2021)

这张封面图片显示了独特的钟状 [Ga ₅ ] 星团及其对应的 ELI-D 最大值，位于一幅老式钟的图画前。首先在相关化合物 Eu ₃ Li ₅ Ga _{5 中}观察到这些团簇是第一个也是唯一一个已知的非凸面镓团簇，这使得对团内键合的研究特别感兴趣。最初受到铕存在的阻碍，由于没有f电子，Sr ₃ Li ₅ Ga ₅可以应用电子定位方法 (ELI-D) 。在我们的文章 202100147 中详细描述了由此产生的对结合情况的洞察。

更新日期：2021-09-21

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11