Constructing a triangular metallacycle with salen–Al and its application to a catalytic cyanosilylation reaction,Chemical Communications

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Constructing a triangular metallacycle with salen–Al and its application to a catalytic cyanosilylation reaction
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-11 , DOI: 10.1039/d1cc04577f
Jun Xu ₁ , Yueyue Zhang ₁ , Jinjin Zhang ₁ , Yang Li ₁ , Bo Li ₁ , Huayu Qiu ₁ , Pengfei Zhang ₁ , Shouchun Yin ₁

Affiliation

A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen–Al complex and a 60° diplatinum(II) acceptor in a 1 : 1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.

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