Molecular structures and magnetic properties of endohedral metallofullerenes,Chemical Communications

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Molecular structures and magnetic properties of endohedral metallofullerenes
Chemical Communications ( IF 4.3 ) Pub Date : 2021-09-07 , DOI: 10.1039/d1cc04218a
Wang Li _{1,

2} , Chunru Wang ₁ , Taishan Wang ₁

Affiliation

Endohedral metallofullerenes have fascinating core–shell structures, with metal atoms or metal clusters encaged in fullerene cages, and they display various chemical, optical and magnetic properties derived from different types of fullerene cages and metal moieties. Fullerene cages can act as carriers to stabilize unusual cluster moieties. Many bizarre species that are hard to produce via synthetic methods survive well under the protection of a fullerene cage, making metallofullerenes ideal platforms for generating new clusters and bonds. Fullerene cages can also be carriers to hold active unpaired electrons. Some metallofullerenes possess electron spin and show intriguing magnetic properties, making them applicable for use in quantum computing, high density information storage and magnetoreception systems. The exploration of new metallofullerenes is still ongoing, while function-oriented studies are also promoted for the future application of metallofullerenes. Herein, we highlight the recent progress in the synthesis, electron spin characteristics and magnetic properties of metallofullerenes. Discussions and an outlook on the future development of metallofullerenes are also stated.

中文翻译：

内嵌金属富勒烯的分子结构和磁性

内嵌金属富勒烯具有迷人的核壳结构，金属原子或金属簇包裹在富勒烯笼中，并且它们显示出源自不同类型富勒烯笼和金属部分的各种化学、光学和磁性特性。富勒烯笼可以作为载体来稳定不寻常的簇部分。许多奇异的物种难以通过合成方法在富勒烯笼的保护下可以很好地生存，使金属富勒烯成为生成新簇和键的理想平台。富勒烯笼也可以作为载流子来保持活跃的不成对电子。一些金属富勒烯具有电子自旋并显示出有趣的磁性，使其适用于量子计算、高密度信息存储和磁接收系统。新型金属富勒烯的探索仍在进行中，同时也促进了功能导向的研究，以促进金属富勒烯的未来应用。在此，我们重点介绍了金属富勒烯的合成、电子自旋特性和磁性方面的最新进展。还陈述了对金属富勒烯未来发展的讨论和展望。

更新日期：2021-09-20

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