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Fast curing unidirectional carbon epoxy prepregs based on a semi-latent hardener: The influence of ambient aging on the prepregs Tg0, processing behavior and thus derived interlaminar performance of the composite
Composites Science and Technology ( IF 8.3 ) Pub Date : 2021-09-20 , DOI: 10.1016/j.compscitech.2021.109047
Fabian Hübner 1 , Johannes Meuchelböck 1 , Felipe Wolff-Fabris 2 , Martin Mühlbach 2 , Volker Altstädt 1 , Holger Ruckdäschel 1
Affiliation  

The aging behavior of a fast-curing epoxy resin (EP) was examined over three months in unidirectional carbon fiber prepregs for the first time. The semi-latent, 120 °C curing one-pot formulation was developed based on industry-grade diglycidyl ether of bisphenol A (DGEBA) resins without the necessity of B-staging, to fully monitor the property change by aging without any post-processing influence. To extend the shelf-life compared to standard wet EP systems, the latent dicyandiamide (DICY) and a semi-latent urea-based catalyst were used, leading to full conversion within 15 min. The conversion was monitored by increasing Tg0 and rheology. High quality unidirectional carbon prepregs were manufactured and then investigated over three months regarding tackiness and resin flow. In parallel, laminates were autoclave-manufactured to evaluate the aging influence on the interlaminar properties. Thus, a correlation between decreasing gel-time, interlaminar adhesion and resulting multiple crack growth was observed via GIC and interlaminar shear strength (ILSS) testing. The investigations show a clear influence of the consolidation quality of the prepregs based on ILSS values and GIC values. A decrease of 19% in ILSS and combined with an erroneous increase of 63% of the GIC due to multiple delamination was observed in the worst case.



中文翻译:

基于半潜伏性硬化剂的快速固化单向碳环氧预浸料:环境老化对预浸料 Tg0、加工行为以及由此得出的复合材料层间性能的影响

快速固化环氧树脂 (EP) 的老化行为首次在单向碳纤维预浸料中进行了三个月以上的测试。基于工业级双酚 A 缩水甘油醚 (DGEBA) 树脂开发的半潜伏、120 °C 固化一锅配方,无需进行 B 阶段,完全监控老化导致的性能变化,无需任何后处理影响。与标准湿 EP 系统相比,为了延长保质期,使用了潜伏双氰胺 (DICY) 和半潜伏尿素基催化剂,从而在 15 分钟内实现完全转化。通过增加Tg0监测转化率和流变学。制造了高质量的单向碳预浸料,然后在三个月内对粘性和树脂流动性进行了调查。同时,通过高压釜制造层压板以评估老化对层间性能的影响。因此,通过G IC和层间剪切强度 (ILSS) 测试观察到凝胶时间减少、层间粘附和由此产生的多裂纹扩展之间的相关性。研究表明基于 ILSS 值和G IC值的预浸料固结质量有明显影响。在最坏的情况下,观察到ILSS 下降 19%,同时由于多次分层导致G IC错误增加 63% 。

更新日期:2021-09-23
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