The adsorption of iodine by porous organic polymers is an active research topic. Two new thiol-linked conjugated microporous polymers (SHCMPs) were successfully prepared by thioalkynes click polymerization. Lone pair electrons of heteroatoms can enhance the interaction between adsorbent and adsorbate, the ability of adsorbent to capture iodine can be improved by introducing electron-rich groups such as nitrogen, thiophene, fluorine, etc. The saturated iodine adsorption capacities of SHCMP-1 and SHCMP-2 are 590 and 495 wt.%, respectively. In addition, SHCMP-2 performs well in detecting Fe³⁺ in aqueous solution, which has potential importance for industrial application of water treatment.

多孔有机聚合物对碘的吸附是一个活跃的研究课题。通过硫炔点击聚合成功制备了两种新型硫醇连接的共轭微孔聚合物（SHCMPs）。杂原子的孤对电子可以增强吸附剂与被吸附物之间的相互作用，通过引入氮、噻吩、氟等富电子基团可以提高吸附剂对碘的捕获能力。 SHCMP-1 和SHCMP-2 分别为 590 和 495 重量％。此外，SHCMP-2在检测水溶液中的Fe ^{3+ 方面}表现良好，对水处理的工业应用具有潜在的重要性。